Colonal Don Juan Vicente was the son of Juan de Bolivar y Martinez de Villegas.
Husband of Dona Maria de la Conception Palacio y Blanco.
Father of Juan Vicente (Marquis de San Luis and Vizconde de Cocorote), Simon Bolivar, María Antonia, Juana, and María del Carmen who died at birth.
Juan died in his sleep in Jan, 1786. His son Simon (born July 1783) was 2.5 years old at the time of his death.