Royalty. Born the daughter of Maximilian von Pfalz-Zweibrücken and his first wife Auguste Wilhelmine von Hessen-Darmstadt. She married the crown prince Wilhelm of Württemberg in 1808. The marriage was very unhappy and was anulled in 1816. In the same year she married Emperor Franz I who had already been widowed three times. After her husbands death she lived in Salzburg.